A UT Dallas Chemist Explains How to Scientifically Smoke a Brisket (2024)

Outside Ten50 BBQ in Richardson, the smell of smoked meats hung in the air on a hot day in June. Dozens were lined up during the lunch hour to order heaping trays of smoked brisket, turkey, and pork before heading inside.

A few weeks ago, UT Dallas professor Jeremiah Gassensmith brought his students to Ten50 for a tasting for a class called the History and Science of Barbecue.

Gassensmith usually keeps himself busy with an impressive day job. He runs the Gassensmith Lab at the university, where his research focuses on how virus particles interact with organic and solid-state chemistry. One of his lab’s most recent research projects involves delivering vaccines through a puff of gas.

When he’s not in the lab, he’s a self-proclaimed backyard barbecue chef. He taught himself how to cook out of curiosity, though he says sometimes it was out of necessity. He grew up in Indiana, where most dinners consist of meat and potatoes.

“Most of my family, I love them, but they’re not great cooks,” he says.

He says he often found himself looking for different cuisines outside of his community. When he was living in the Midwest, Gassensmith says he found the best barbecue in Black communities.

“It didn’t really permeate very far out of those communities,” he says. “It also wasn’t a place I frequented. When I got it, it was good, and I loved it, but it wasn’t something we could eat a lot of the time.”

Gassensmith says he was determined to “appropriate” the state’s barbecue culture when he got to Texas with his wife. He bought the cheapest smoker he could find, so cheap that he had to wrap it in thermal insulation to keep the heat inside. He took advantage of what he could and used it as a way to teach himself how to smoke meat.

Chemistry and barbecue have always gone hand-in-hand, Gassensmith says, but he didn’t fully appreciate the link until after he started smoking. Unlike cooking on a stovetop, which is essentially heating food on top of something hot, barbecue involves closely monitoring thermodynamics and reactions.

“It was advanced chemistry,” he says. “It was the sort of thing that makes sophom*ores really upset when they have to learn it.”

Barbecuing and smoking involve watching how heat affects the meat. The temperature and length of time meat is smoked changes the taste and texture. Rendering fat, for example, is more than just putting a fatty piece of meat on a hot pan. Rendering fat means destroying cell membranes: if it’s too hot, the fat will surely melt, but all the proteins will fry up and burn, and it’ll taste bad. To render fat correctly, it must be done at a low temperature to control the reaction.

Barbecuing is a Maillard reaction, or a chemical reaction between proteins, fats, and sugars that cause the browning of the meat. Maillard reactions are also found in whiskeys, bread, toffee, and roasted peanuts.

“You have to access this narrow range of chemistry with your temperature, and that chemistry takes a while to happen,” he says. “It’s literally waiting for proteins to unfold, and that process goes very slowly if you want them to unfold in just the right way.”

Brisket should fall apart—that’s usually a good sign the right chemical reactions took place. Brisket and pork shoulder, two of the most popular smoked meats, come from heavily used parts of an animal. When cooked incorrectly, the meat turns out chewy and tough.

Cooking the meat slow and low breaks down collagen, which looks like three strands of twisted yarn. When heat is applied—ideally between 160 to 180 degrees Fahrenheit, Gassensmith says—collagen loosens and melts, and it can bind with water to keep the meat moist. Too little heat results in chewy meat, and too much heat means the collagen tightens and makes the meat dry. Dry brining the meat with salt for a few hours can help with this; salt can “wedge” itself into the collagen strands, keeping them open for more water to be absorbed.

When Gassensmith started smoking his own brisket, he approached it the way he would any experiment. He determined the most important variables to see where adjustments needed to be made. In this case, the most important variables are temperature, meat quality, and time. His go-to is a 10 to 15-pound prime cut brisket. He uses multiple thermometer probes to monitor the temperature, which can vary based on the size of the meat.

He also sprays his meats with water as they’re smoking. Smoke binds to water and helps give barbecued meat its signature smoky taste. It also keeps the meat moist, but only if everything else has been done correctly: meat has been brined, collagen is loose, and the temperature is consistent. Gassensmith admits, though, that chemistry isn’t all that goes into barbecuing.

“It’s an art,” he says. “Every piece is going to be different. You can apply the scientific method only so far.”

During his class, Gassensmith asked his students to read Black Smoke: African Americans and the United States of Barbeque by Adrian Miller, and Smokelore: A Short History of Barbeque in America by Jim Auchmutey. Both books explore the origin of barbecue in this country.

During the colonial era, European settlers arriving in the Americas observed the Taino people of the Caribbean using a wooden structure called a barbacoa for slow-cooking meat over a fire pit. The term “barbecue” originates from the Taino word “barbacoa.”

“[Barbecue] was propagated in the United States by European immigrants,” Gassensmith says. “To understand how that spread and evolved requires you to understand a lot about the history of Black migration in the United States.”

In the South, enslaved people were skilled in smoking and pit-roasting. They played a crucial role in shaping southern barbecue traditions. They introduced new flavors, spices, and methods of cooking that became integral to the development of American barbecue.

In Texas, beef is the star of barbecue. But as Black communities migrated north, pitmasters applied their cooking knowledge to other meats, like pork and chicken. Barbecue techniques were influenced by local flavors, even down to the sauces. (Carolina barbecue sauces usually have a vinegar base, while Kansas City barbecue sauce is sweet and spicy.) The result is regional barbecue styles all over the country, such as Memphis, Carolina, Kansas City, and Alabama. Each has its own story and unique history.

“Since barbecue is just this incredibly uniquely American dish, I thought it was a great way to teach American history was through food,” he says.

Gassensmith’s Barbecue Tips

Get a great—not just good—cut of meat

Barbecue starts with a solid base, and that means three ingredients: salt, pepper, and a dang good cut of meat. For brisket, Gassensmith uses prime, which means ample amounts of fat are marbled in the meat. “You can’t hide behind lower quality cuts of meat,” Gassensmith says. “Do yourself a favor and get a nice cut.”

Use water to cool it down and develop a crust

Gassensmith prefers using water while smoking the meat. A spritz helps keep the meat juicy and gives it a smoky crust, because smoke likes to bind to water. It also helps regulate the temperature of the meat.

Closely monitor the temperature

Gassensmith uses multiple thermometers when he smokes meat. He uses a six-probe thermometer, but at least two should do the job, he says: one thermocouple sensor inside the smoker and a quick read thermometer in the middle of the piece of meat. The thermocouple should read around 250 degrees Fahrenheit for brisket and 300 degrees Fahrenheit for pork.

After it’s done, resting will help the brisket cook a little bit more help and further render fat or break down collagen, Gassensmith says, but it doesn’t help soak up any juices.

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A UT Dallas Chemist Explains How to Scientifically Smoke a Brisket (1)

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A UT Dallas Chemist Explains How to Scientifically Smoke a Brisket (2024)

FAQs

What is the science behind smoking a brisket? ›

But if you smoke or slow roast something, like a brisket, then the collagen breaks down and melts. While melting, water gets into this collagen, and creates gelatin, basically giving you meat jello, which makes your meal tender, juicy, and flavorful.

What is the process of smoking a brisket? ›

Rub the brisket with mustard or olive oil and apply the seasoning evenly over all sides of the brisket. Place the brisket in the smoker with the point side (thicker side) facing the fire box. Close the lid and don't open it for 6 to 8 hours, or until the internal temperature reaches 165°F.

What is the secret to smoking brisket? ›

Slow-smoke at a temperature of 250˚F, allowing about one hour of cooking time per pound of meat. So, if you have a 10-pound brisket, expect to smoke it for about 10 hours. Keep the fat side up so the juices can drip through the meat. Wrap in foil.

What is the chemistry behind smoking meat? ›

The smoke ring involves the chemistry of nitric oxide from burning wood combining with myoglobin in meat to form nitrosyl hemochromogen, the same pigment found in cured meats. This is why you do not see this phenomenon in meats cooked in the oven since there is no source of nitric oxide in this environment.

What is the science behind smoke flavor? ›

Smoke is made up of gases, water vapor and small solid particles from the fuel. Burning wood breaks down molecules called lignans, and these turn into smaller organic molecules – including syringol and guaiacol – that are mainly responsible for the quintessential smoky flavor.

Does brisket have a lot of collagen? ›

Since brisket has a lot of connective tissue, that means it contains a lot of collagen, the most abundant protein in the body. Collagen is necessary for joint health and firm skin. High levels of oleic acid are found in brisket meat. This helps lower bad cholesterol while raising levels of the good variety.

What is the 3/2:1 rule for brisket? ›

Often used for other meats that require long, slow cooking on the barbecue, such as ribs, the 3-2-1 method essentially involves firstly smoking the meat as it is for three hours, wrapping it for the second two hours, and finally finishing the cooking unwrapped for the last hour.

Is it better to smoke brisket at 225 or 250? ›

I think the sweet spot for brisket is 225-250°F. This low temperature allows the brisket to render nice and slowly while having enough time to absorb all that smoke flavor. Cooking a brisket hot and fast can tighten up the connective tissue in the meat which will leave it tough and chewy.

How long to smoke a 5 lb brisket at 225 degrees? ›

A: You can usually figure about 1.5 hours per pound at 225 degrees for brisket, pork shoulder and other larger pieces of meat. Several things can affect this time such as actual meat thickness, wind, temperature and how often you open the door of the smoker.

What not to do when smoking a brisket? ›

12 Brisket Mistakes Everyone Should Avoid
  1. Cooking at the Wrong Temperature. ...
  2. Using the Wrong Rub. ...
  3. Not Allowing (More Than) Enough Time to Smoke. ...
  4. Not Letting Brisket Rest Long Enough. ...
  5. Making Too Many Changes Between Cooks. ...
  6. Only Looking at Time and Temperature Before Wrapping. ...
  7. Spraying the Fat. ...
  8. Over or Under Smoking the Meat.

What is the key to a juicy brisket? ›

Here are some quick tips:
  1. You need offset smoke. You can do this with a kettle grill. ...
  2. You can't un-burn BBQ. So go ahead and be cautious with the fire temperature. ...
  3. Go ahead and cut your brisket in half. ...
  4. Use a water pan to add moisture.
  5. Spray (mop) the brisket when you look at it. ...
  6. Take the brisket off at 203.
May 20, 2023

What makes brisket so naturally flavorful? ›

During the cooking process, the surface of the brisket is exposed to heat, which causes the Maillard reaction to occur. This reaction creates a complex array of flavor compounds, including compounds that contribute to the meaty, savory flavors often associated with brisket.

What is the science behind the brisket stall? ›

As the meat heats up, the water within its cells begins to evaporate. This evaporation cools down the surface, counteracting the rise in internal temperature and resulting in the stall. The breakdown of collagen and connective tissues within the brisket also contributes.

Why is smoked brisket so good? ›

Brisket has a dense, savory, beefy flavor like lean steak. When cooked properly, it is very tender with natural juices in every bite -- similar to a fattier steak like a ribeye. Smoked brisket also has the flavors of the natural wood used in the cooking process.

What gives brisket a smoke ring? ›

Rather, the smoke ring is caused by a chemical reaction between the meat and invisible nitric oxide gas that's produced when wood or charcoal are burned to heat a smoker or grill. A smoke ring is a color change in the meat's myoglobin, the same protein that makes raw beef red.

Why is brisket tough after smoking? ›

Brisket contains a lot of connective tissue, which can make it tough. The type of connective tissue in brisket is called collagen. Cook the meat quickly and you get tough, dry meat. Cook a brisket slowly, with some liquid, and the collagen turns into gelatin.

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